RT Journal Article T1 Metabolic patterns in the lipoxygenase pathway associated to fruitiness attributes of extra virgin olive oil A1 Tome-Rodriguez, Sonia A1 Ledesma-Escobar, Carlos Augusto A1 Penco-Valenzuela, Jose Maria A1 Calderon-Santiago, Monica A1 Priego-Capote, Feliciano K1 Extra virgin olive oil K1 Fruitiness K1 Volatiles K1 Metabolomics K1 Multivariate ROC analysis K1 Lipoxygenase pathway AB Fruitiness is one of the most appreciated organoleptic features of extra virgin olive oils (EVOOs), which are categorized as a function of the fruitiness intensity and typology. In this research, we determined the main C-5 and C-6 volatiles formed through the lipoxygenase pathway (LOX) in 200 EVOOs produced in two agronomic seasons. Multivariate analysis was applied to find discrimination patterns in the concentrations of volatiles in EVOOs, which were tasted and classified in terms of fruitiness by the Panel Test. Multivariate ROC analysis of metabolic ratios governing the formation of C(5 )and C(6 )volatiles allowed identifying the main enzymatic steps contributing to explain chemical differences in the volatile composition of EVOOs. Fruitiness intensity was specially explained by the conversion of 3-hexenal to 2-hexenol and 3-hexenol, whereas the type of fruitiness was conditioned by the three branches of the LOX pathway that lead to the formation of C-5 and C-6 volatiles. PB Academic press inc elsevier science SN 0889-1575 YR 2022 FD 2022-02-18 LK http://hdl.handle.net/10668/22303 UL http://hdl.handle.net/10668/22303 LA en NO Tomé-Rodríguez S, Ledesma-Escobar CA, Penco-Valenzuela JM, Calderón-Santiago M, Priego-Capote F. Metabolic patterns in the lipoxygenase pathway associated to fruitiness attributes of extra virgin olive oil. Journal Of Food Composition And Analysis [Internet]. 1 de junio de 2022;109:104478. Disponible en: https://doi.org/10.1016/j.jfca.2022.104478 DS RISalud RD Apr 12, 2025