RT Journal Article
T1 Benzotriazole-based multidonor-acceptor systems as attractive two-photon absorption dye platforms
A1 Benitez-Martin, Carlos
A1 Donoso, Beatriz
A1 Torres-Moya, Ivan
A1 Herrera, Jesus
A1 Diaz-Ortiz, Angel
A1 Najera, Francisco
A1 Prieto, Pilar
A1 Perez-Inestrosa, Ezequiel
K1 Two-photon absorption
K1 Fluorescence
K1 DFT calculations
K1 Benzotriazole dyes
K1 Optical-data storage
K1 Absorbing chromophores
K1 Fluorescent-probe
K1 Red-fluorescent
K1 Wave-guide
K1 Design
K1 Benzothiadiazole
K1 Emission
K1 Thiadiazoloquinoxaline
K1 Initiators
AB Pyrazine-decorated benzotriazole cores allow the orthogonal combination of two dipolar systems within a single molecule. A series of this type of derivatives was synthesized and their photophysical features were studied. The properties of these compounds showed remarkable differences in function depending on the substitution in the pyrazine ring of the benzotriazole core. Furthermore, the two-photon absorption property (2PA) was studied to determine the structure-properties relationship for the reported compounds. The best dye achieved a crosssection of 1532 GM, which was higher than values previously obtained for similar D-pi-A-pi-D benzotriazole derivatives. TD-DFT calculations, which supported the experimental observations, indicating the interaction between the two dipolar systems was responsible for enhancing the 2 PA properties and favoring bathochromic shifts.
PB Elsevier
SN 0143-7208
YR 2022
FD 2022-02-09
LK http://hdl.handle.net/10668/22157
UL http://hdl.handle.net/10668/22157
LA en
NO Benitez-Martin C, Donoso B, Torres-Moya I, Herrera J, Díaz-Ortiz Á, Najera F, et al. Benzotriazole-based multidonor-acceptor systems as attractive twophoton absorption dye platforms. Dyes and Pigments. 2022, (200). 110149
DS RISalud
RD Apr 6, 2025