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Dibenzocycloheptatriene as end-group of Thiele and tetrabenzo-Chichibabin hydrocarbons.

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dc.contributor.authorJiménez, Vicente G
dc.contributor.authorMayorga-Burrezo, Paula
dc.contributor.authorBlanco, Victor
dc.contributor.authorLloveras, Vega
dc.contributor.authorGómez-García, Carlos J
dc.contributor.authorŠolomek, Tomáš
dc.contributor.authorCuerva, Juan M
dc.contributor.authorVeciana, Jaume
dc.contributor.authorCampaña, Araceli G
dc.date.accessioned2023-02-09T09:41:30Z
dc.date.available2023-02-09T09:41:30Z
dc.date.issued2020-09-23
dc.description.abstractThiele (Th) and tetrabenzo-Chichibabin (TBC) derivatives with terminal dibenzocycloheptatriene (DBHept) units were prepared. A clear correlation between their electronic and molecular structures was stablished. Insights into their closed- or open-shell ground states were gained, where particular contribution of the heptagonal carbocycles as end-groups was proved. Remarkably, a thermally accessible triplet diradical configuration was confirmed for the DBHept-TBC compound.
dc.identifier.doi10.1039/d0cc04489j
dc.identifier.essn1364-548X
dc.identifier.pmid32966400
dc.identifier.unpaywallURLhttps://pubs.rsc.org/en/content/articlepdf/2020/cc/d0cc04489j
dc.identifier.urihttp://hdl.handle.net/10668/16302
dc.issue.number84
dc.journal.titleChemical communications (Cambridge, England)
dc.journal.titleabbreviationChem Commun (Camb)
dc.language.isoen
dc.organizationIBS
dc.page.number12813-12816
dc.pubmedtypeJournal Article
dc.rightsAttribution-NonCommercial 4.0 International
dc.rights.accessRightsopen access
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/
dc.titleDibenzocycloheptatriene as end-group of Thiele and tetrabenzo-Chichibabin hydrocarbons.
dc.typeresearch article
dc.type.hasVersionVoR
dc.volume.number56
dspace.entity.typePublication

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